PROCESS FOR PREPARING PYRIDINE CARBOXYLIC ACID ESTERS

A novel method is disclosed for the preparation of 2,3-pyridine-dicarboxylates by the reaction of a ketoester such as dimethyl oxalacetate with an .alpha.,.beta.-unsaturated aldehyde or ketone such as 2-ethylacrolein and at least 1 molar equivalent of ammonium salt in suitable solvent utilizing a de...

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Bibliographische Detailangaben
Hauptverfasser: MUELLER, WERNER H, GUPTON, B. FRANKLIN, REA, JAMES H
Format: Patent
Sprache:eng ; fre
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Zusammenfassung:A novel method is disclosed for the preparation of 2,3-pyridine-dicarboxylates by the reaction of a ketoester such as dimethyl oxalacetate with an .alpha.,.beta.-unsaturated aldehyde or ketone such as 2-ethylacrolein and at least 1 molar equivalent of ammonium salt in suitable solvent utilizing a dehydrogenation catalyst such as palladium on carbon.