PROCESS FOR PRODUCING UNSATURATED HYDROCARBONS

A process for producing unsaturated hydrocarbons which comprises contacting of paraffin, monoolefine and/or alkylaromatic compounds with a catalyst at a temperature within the range of from 400 to 700.degree.C in the presence of an inert gas and/or steam. The catalyst comprises a carrier with deposi...

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Hauptverfasser: KOROTKEVICH, BORIS S, TMENOV, DZANTEMIR N, MALOV, EVGENY A, DVORETSKY, MIKHAIL L, KANDALOVA, VALENTINA D, VASILIEV, GAVRIL I, SHMUK, JURY A, LUKYANENKO, VALERY P, ZHESTOVSKY, GENNADY P, TABAKOV, ALBERT V, SHAPOVALOVA, LIDIA P, LUKASHOV, ANATOLY I, SVINTSOV, NIKOLAI I, POLATAIKO, ROMAN I
Format: Patent
Sprache:eng ; fre
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Zusammenfassung:A process for producing unsaturated hydrocarbons which comprises contacting of paraffin, monoolefine and/or alkylaromatic compounds with a catalyst at a temperature within the range of from 400 to 700.degree.C in the presence of an inert gas and/or steam. The catalyst comprises a carrier with deposited thereonto an oxide compound of molybdenum in an amount of from 5 to 35% by weight of the catalyst. As the carrier use is made of a granulated porous crystalline silica modified with magnesia in an amount of from 1 to 20% by weight of TiO2, or a granulated magnesium-aluminium carrier consisting of 70 to 95% by weight of MgO and 5 to 30% by of from 400 to 700.degree.C till restoratio of catalytic activity of the catalyst. The process according to the present invention ensures a high selectivity; substantially simplifies temperature control in the reaction zone; avoids the possibility of formation of a hazardous mixture of hydrocarbons with oxygen; simplifies purification of waste waters.