polimerização de etileno em um reator a alta pressão com alimentação aperfeiçoada de iniciadores

Process for the preparation of ethylene homopolymers or copolymers in a high pressure reactor with at least two spatially separated initiator injection points by polymerizing ethylene and optionally further monomers in the presence of at least two different mixtures of free-radical polymerization in...

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Bibliographische Detailangaben
Hauptverfasser:	DIETER LITTMANN, ANDRE-ARMAND FINETTE, JÜRGEN PETER MOHRBUTTER, SVEN GEORG WOLFRAM
Format:	Patent
Sprache:	por
Schlagworte:	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	Process for the preparation of ethylene homopolymers or copolymers in a high pressure reactor with at least two spatially separated initiator injection points by polymerizing ethylene and optionally further monomers in the presence of at least two different mixtures of free-radical polymerization initiators at from 100° C. to 350° C. and pressures in the range of from 160 MPa to 350 MPa, wherein the process comprises the following steps: a) providing at least two different initiators as solution in a suitable solvent or in liquid state, b) mixing the initiators and optionally additional solvent in at least two static mixers and c) feeding each of the mixtures to a different initiator injection point of the high pressure reactor, and apparatus for feeding initiator mixtures to a high pressure reactor with at least two spatially separated initiator injection points.