processo para a preparação de um alquileno glicol a partir de um óxido de alquileno

The invention provides a process for the preparation of an alkylene glycol from an alkylene oxide. Alkylene oxide reacts with carbon dioxide in the presence of a carboxylation catalyst to provide alkylene carbonate; alkylene carbonate reacts with water in the presence of a hydrolysis catalyst to pro...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Abraham Adriaan Smardijk, Eugene Marie Godfried Andre Van Kruchten, Hendrik Stichter
Format: Patent
Sprache:por
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Beschreibung
Zusammenfassung:The invention provides a process for the preparation of an alkylene glycol from an alkylene oxide. Alkylene oxide reacts with carbon dioxide in the presence of a carboxylation catalyst to provide alkylene carbonate; alkylene carbonate reacts with water in the presence of a hydrolysis catalyst to provide alkylene glycol. An initial charge of the carboxylation catalyst and an initial charge of the hydrolysis catalyst are added, the degradation and activity of the hydrolysis catalyst are monitored, and when the activity of the hydrolysis catalyst has fallen below a minimum level, an additional charge of the hydrolysis catalyst is added.