Processos para a preparação de compostos, e seus enantiômeros
A process for producing compounds of formula (VIIa) and (VIIb) wherein X is a leaving group; Y and Y are idependently Cl or Br; and Z is Cl, Br or a haloalkyl group which process comprises a) reacting a compound of formula (VII) wherein X, Y, Y and Z are as defined for compounds (VIIa) and (VIIb) wi...
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Zusammenfassung: | A process for producing compounds of formula (VIIa) and (VIIb) wherein X is a leaving group; Y and Y are idependently Cl or Br; and Z is Cl, Br or a haloalkyl group which process comprises a) reacting a compound of formula (VII) wherein X, Y, Y and Z are as defined for compounds (VIIa) and (VIIb) with a substantially optically pure chiral amine in a solvent to form a diastereoisomeric salt; b) separating the diastereomeric salt of each enantiomer; c) converting the diastereomeric salt of each anantiomer separately to compounds of formulae (VIIa) and (VIIb) respectively by acid or base hydrolysis, the use of the compounds in making pyrethroid insecticides and novel intermediates. |
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