processo integrado para a recuperação simultánea de um cloreto de potássio com um grau industrial e de um sal comestìvel de baixo sódio

Process for simultaneous recovery of KCl and KCl-enriched edible salt comprises: (i) desulphatation of bittern with CaCl2; (ii) subjecting desulphated bittern to evaporation; (iii) mixing desulphated bittern of step (ii) with concentrated MgCl2-solution to obtain carnallite; (iv) decomposing carnall...

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Hauptverfasser: VADAKKE PUTHOOR MOHANDAS, RAJINDER NATH VOHRA, HIMANSHU LABSHANKER JOSHI, ROHIT HARSHADRAY DAVE, ABDULHAMID USMANBHAI HAMIDANI, RAMJIBHAI DEVJIBHAI RATHOD, HASINA HAJIBHAI DERAIYA, ASHOK KUMAR BHAGVANJIBHAI KASUNDRA, PURASHOTTAMBHAI RAVAJIBHAI JADAV, KOUSHIK HALDER, KAUSHIK JETHALAL LANGALIA, MAHESHKUMAR RAMNIKLAL GANDHI, PUSHPITO KUMAR GHOSH, SOHANLAL DAGA
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Sprache:por
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Zusammenfassung:Process for simultaneous recovery of KCl and KCl-enriched edible salt comprises: (i) desulphatation of bittern with CaCl2; (ii) subjecting desulphated bittern to evaporation; (iii) mixing desulphated bittern of step (ii) with concentrated MgCl2-solution to obtain carnallite; (iv) decomposing carnallite with water to obtain KCl and residual bittern; (v) concentrating residual bittern to obtain NaCl and KCl in bittern as crude carnallite and carnallite decomposed liquor; (vi) decomposing crude carnallite of step (v) with water to produce KCl-enriched low sodium salt, as well as carnallite decomposed liquor; (vii) collecting carnallite decomposed liquor of steps (v) and (vi) and treating with lime to generate Mg(OH)2 and filtrate containing CaCl2 and KCl; (viii) recycling the filtrate of step (vii) to step (i), while recovering KCl lost in carnallite decomposed liquor; (ix) recycling end bittern of step (iii) for production of carnallite and CaCl2; (x) utilizing excess MgCl2 to recover bromine and obtain MgCl2.6H2O.