CATALYTIC POLYMERISATION OF OLEFINS

A process for the preparation of homopolymers and copolymers of alpha -monoolefins by means of a Ziegler-Natta catalyst system comprising (1) a halide of trivalent titanium, (2) an oxygen compound (ester) having a specific formula and (3) an aluminum-alkyl, the titanium halide (1) and the oxygen com...

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Bibliographische Detailangaben
1. Verfasser:	G. STAIGER
Format:	Patent
Sprache:	eng
Schlagworte:	CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP
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Beschreibung
Zusammenfassung:	A process for the preparation of homopolymers and copolymers of alpha -monoolefins by means of a Ziegler-Natta catalyst system comprising (1) a halide of trivalent titanium, (2) an oxygen compound (ester) having a specific formula and (3) an aluminum-alkyl, the titanium halide (1) and the oxygen compound (2) being milled together before use, wherein the catalyst system employed contains, as a further component, (4) a phenolic compound of the formula where R3 is C1-C6-alkyl, R4 is hydrogen or C1-C6-alkyl, p is an integer from 0 to 5 and q is an integer from 1 to 5.