PROCESS FOR MANUFACTURE OF GLYCOSIDES IN PRESENCE OF METAL FLUORIDE

A process for the manufacture of glycosides which comprises reacting a protected hexopyranosyl fluoride with an aglycon or a silyl ether thereof in the presence of a metal fluoride of group IV or V of the periodic table, said metal having an atomic number of at least 22 and being present in the fluo...

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Bibliographische Detailangaben
Hauptverfasser: WOLFRAM FRITSCHE-LANG, MATTHIAS KREUZER, JOACHIM THIEM, MERTEN SCHLINGMANN, HANS-MATTHIAS DEGER
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:A process for the manufacture of glycosides which comprises reacting a protected hexopyranosyl fluoride with an aglycon or a silyl ether thereof in the presence of a metal fluoride of group IV or V of the periodic table, said metal having an atomic number of at least 22 and being present in the fluoride in a higher, stable and non-oxidizing or weekly oxidizing stage.