Smoking article comprising aerogel

A smoking article is provided that includes an aerogel, which can be optionally impregnated with a catalytic metal compound or can optionally be coated with at least one aerosol-forming material and a flavoring agent. The smoking article comprises various segments such as a heat generation segment, an aerosol-generation segment, and a mouth end. The aerogel can be placed near or within any of these segments. The presence of the aerogel can reduce the concentration of certain gaseous components of mainstream smoke generated during use of a smoking article incorporating a heat generation segment containing a fuel element.