Blow molding resins with improved ESCR

Polyethylene resins having improved environmental stress crack resistance, stiffness and impact resistance is made by a process comprising feeding both a chromium oxide catalyst and a silyl chromium catalyst into a polymerization reactor. The chromium oxide catalyst and the silyl chromium catalyst a...

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Hauptverfasser: ROBERT J. JORGENSEN, KAREN BREETZ, STEPHEN PAUL JAKER, CLIFF ROBERT MURE, GUYLAINE ST. JEAN
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creator ROBERT J. JORGENSEN
KAREN BREETZ
STEPHEN PAUL JAKER
CLIFF ROBERT MURE
GUYLAINE ST. JEAN
description Polyethylene resins having improved environmental stress crack resistance, stiffness and impact resistance is made by a process comprising feeding both a chromium oxide catalyst and a silyl chromium catalyst into a polymerization reactor. The chromium oxide catalyst and the silyl chromium catalyst are on separate supports. The chromium oxide catalyst is 25-50 weight percent and the silyl chromium catalyst is 50-75 weight percent of the total weight of catalyst. The catalysts may be added separately or as a single mixture.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title Blow molding resins with improved ESCR
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