Blow molding resins with improved ESCR

Blow molding resins with improved ESCR

Polyethylene resins having improved environmental stress crack resistance, stiffness and impact resistance is made by a process comprising feeding both a chromium oxide catalyst and a silyl chromium catalyst into a polymerization reactor. The chromium oxide catalyst and the silyl chromium catalyst a...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: ROBERT J. JORGENSEN, KAREN BREETZ, STEPHEN PAUL JAKER, CLIFF ROBERT MURE, GUYLAINE ST. JEAN
Format: Patent
Sprache:eng
Schlagworte:
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
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Beschreibung
Zusammenfassung:Polyethylene resins having improved environmental stress crack resistance, stiffness and impact resistance is made by a process comprising feeding both a chromium oxide catalyst and a silyl chromium catalyst into a polymerization reactor. The chromium oxide catalyst and the silyl chromium catalyst are on separate supports. The chromium oxide catalyst is 25-50 weight percent and the silyl chromium catalyst is 50-75 weight percent of the total weight of catalyst. The catalysts may be added separately or as a single mixture.