Process for the preparation of a highly linear alcohol composition

Process for the preparation of a highly linear alcohol composition is provided comprising the steps of:(a) reacting carbon monoxide with hydrogen under Fischer-Tropsch reaction conditions in the presence of a Fischer-Tropsch catalyst comprising cobalt;(b) separating from the product of step (a) at l...

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Hauptverfasser:	HENDRIK DIRKZWAGER, AREND HOEK, JOHANNES IGNATIUS GEIJSEL, LAURENT ALAIN FENOUIL, FREDERIK HENDRIK VAN DER STEEN
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMISTRY CRACKING HYDROCARBON OILS FUELS GENERAL METHODS OF ORGANIC CHEMISTRY LUBRICANTS METALLURGY MINERAL WAXES ORGANIC CHEMISTRY PEAT PETROLEUM, GAS OR COKE INDUSTRIES PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE
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Beschreibung
Zusammenfassung:	Process for the preparation of a highly linear alcohol composition is provided comprising the steps of:(a) reacting carbon monoxide with hydrogen under Fischer-Tropsch reaction conditions in the presence of a Fischer-Tropsch catalyst comprising cobalt;(b) separating from the product of step (a) at least one hydrocarbon fraction comprising between 10 and 50% by weight of olefins containing 6 or more carbon atoms;(c) contacting one or more of the hydrocarbon fractions obtained in step (b) with carbon monoxide and hydrogen under hydroformylation conditions in the presence of a hydroformylation catalyst based on a source of cobalt and one or more alkyl phosphines; and(d) recovering the alcohol composition.