Enhanced water resistance of starch-based materials

Molded products made from gelatinized starch can be made water-resistant by coating with biodegradable polyesters such as poly(beta-hydroxybutyrate-co-valerate) (PHBV), poly(lactic acid) (PLA), and poly(+531 -caprolactone) (PCL). Adherence of the two dissimilar materials is achieved through the use...

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Bibliographische Detailangaben
Hauptverfasser: RANDAL L. SHOGREN, JOHN W. LAWTON JR
Format: Patent
Sprache:eng
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Zusammenfassung:Molded products made from gelatinized starch can be made water-resistant by coating with biodegradable polyesters such as poly(beta-hydroxybutyrate-co-valerate) (PHBV), poly(lactic acid) (PLA), and poly(+531 -caprolactone) (PCL). Adherence of the two dissimilar materials is achieved through the use of an intervening layer of a resinous material such as shellac or rosin which possesses a solubility parameter (hydrophobicity) intermediate to that of the starch and the polyesters. Coating is achieved by spraying an alcoholic solution of the shellac or rosin onto the starch-based article and subsequently coating with a solution of the polyester in an appropriate solvent. Biodegradable products made by the instant process have utility in the food service industry.\!