FESTKÖRPERREICHE BINDEMITTELKOMBINATIONEN UND DEREN VERWENDUNG

Binder comprises crosslinker and graft copolymer resin prepared by copolymerizing: (a) polybutadiene; (b) aromatic monomer; (c) hydroxyalkyl (meth)acrylate; (d) 1-12C cycloaliphatic (meth)acrylate; (e) 1-8C alcohol (meth)acrylate; (f) alpha , beta -unsaturated 3-7C mono- or di-carboxylic acid and/or...

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Bibliographische Detailangaben
Hauptverfasser: WAMPRECHT, CHRISTIAN, SONNTAG, MICHAEL, MUNDSTOCK, HOLGER
Format: Patent
Sprache:ger
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Beschreibung
Zusammenfassung:Binder comprises crosslinker and graft copolymer resin prepared by copolymerizing: (a) polybutadiene; (b) aromatic monomer; (c) hydroxyalkyl (meth)acrylate; (d) 1-12C cycloaliphatic (meth)acrylate; (e) 1-8C alcohol (meth)acrylate; (f) alpha , beta -unsaturated 3-7C mono- or di-carboxylic acid and/or malic (sic) or fumaric acid semi-ester with 1-14C alcohol; and (g) comonomers. Binder mixture comprises 10-50 (10-40) pts. wt. crosslinker(s) and 90-50 (90-60) pts. wt. hydroxy-functional graft copolymer resin prepared by copolymerizing: (a) 0.1-10 pts. wt. polybutadiene of mol. wt. 500-10,000 and with 20% 1,2-vinyl bonds; (b) 5-60 pts. wt. aromatic monomer such as styrene, alpha -methylstyrene or vinyl toluene; (c) 10-50 pts. wt. 2-4C prim. hydroxyalkyl (meth)acrylate; (d) 5-70 pts. wt. 1-12C cycloaliphatic (meth)acrylate; (e) 5-50 pts. wt. 1-8C alcohol (meth)acrylate; (f) 0.1-5 pts. wt. alpha , beta -unsaturated 3-7C mono- or di-carboxylic acid and/or malic or fumaric acid semi-ester with 1-14C alcohol; and (g) 0-40 pts. wt. further comonomers, preferably up to 10 wt.% hydroxypropyl methacrylate.