KONTINUIERLICHES GASPHASENPOLYMERISATIONSVERFAHREN

Continuous gas phase polymerization for producing ethylene homopolymers and -copolymers, comprises polymerizing ethylene or monoolefin from but-1-en, pent-1-en, 2-methylpentene, hex-1-en, hept-1-en and oct-1-en in the a polymerization reactor; and endowing a catalyst poison with boiling point higher...

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Hauptverfasser: KARER, RAINER, MIHAN, SHAHRAM DR, EVERTZ, KASPAR DR, LANGE, ARMIN DR, FEINDT, HANS-JACOB DR, BAUER, PETER, HECKER, MANFRED DR, ROSENDORFER, PHILIPP DR, MICKLITZ, WOLFGANG DR
Format: Patent
Sprache:ger
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Zusammenfassung:Continuous gas phase polymerization for producing ethylene homopolymers and -copolymers, comprises polymerizing ethylene or monoolefin from but-1-en, pent-1-en, 2-methylpentene, hex-1-en, hept-1-en and oct-1-en in the a polymerization reactor; and endowing a catalyst poison with boiling point higher than a circle gas pipeline, and molecular weight greater than 100 g/mol at a position after the reactor, but before the cooler and compressor. Continuous gas phase polymerization for producing ethylene homopolymers and -copolymers, comprises polymerizing ethylene and/or monoolefin from but-1-en, pent-1-en, 2-methylpentene, hex-1-en, hept-1-en or oct-1-en, in the polymerization zone of a gas phase polymerization reactor at 30-125[deg]C and 1-100 bar in the gaseous phase in a finely divided polymer bed, in the presence of a metallocene catalyst in carrier form polymer, where a reactor gas is lead into the circle gas pipeline for the removal of the polymerization heat; and endowing a catalyst poison with boiling point higher than circle gas pipeline and molecular weight greater than 100 g/mol at a position after the reactor but before the cooler and compressor, for preventing polymer linings, such that the productivity of the catalyst is not essentially affected in the reactor.