HERSTELLUNG VON ORGANOLITHIUM- UND ORGANOPHOSPHOR-DERIVATEN

This invention relates to processes for making phosphorus compounds R 2 P-X-PR 2 , R 2 P-M, R 2 P-L and R 3 P, and the novel cation R 2 P + (L)-X-P + (L)R 2 , where R represents an optionally substituted hydrocarbyl group, X represents a bridging group, L represents a leaving group and M represents...

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Hauptverfasser: VAN DER MADE, ALEXANDER, WILLEM, VAN GINKEL, ROELOF, DE WITH, JAN, EILENBERG, WOLF
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creator VAN DER MADE, ALEXANDER, WILLEM
VAN GINKEL, ROELOF
DE WITH, JAN
EILENBERG, WOLF
description This invention relates to processes for making phosphorus compounds R 2 P-X-PR 2 , R 2 P-M, R 2 P-L and R 3 P, and the novel cation R 2 P + (L)-X-P + (L)R 2 , where R represents an optionally substituted hydrocarbyl group, X represents a bridging group, L represents a leaving group and M represents an alkali metal atom. The invention relates further to a process for making a compound R 2 P-L from a compound R-H via a new process for making the compound R-Li followed by its reaction with a compound Hal 2 P-L. The compound R 2 P-X-PR 2 is a ligand suitable for making catalysts for copolymerizing carbon monoxide and an olefinically unsaturated compound.
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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR PREPARATION OR CHEMICAL WORKING-UP
THEIR RELEVANT APPARATUS
TRANSPORTING
title HERSTELLUNG VON ORGANOLITHIUM- UND ORGANOPHOSPHOR-DERIVATEN
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