HERSTELLUNG VON ORGANOLITHIUM- UND ORGANOPHOSPHOR-DERIVATEN

This invention relates to processes for making phosphorus compounds R 2 P-X-PR 2 , R 2 P-M, R 2 P-L and R 3 P, and the novel cation R 2 P + (L)-X-P + (L)R 2 , where R represents an optionally substituted hydrocarbyl group, X represents a bridging group, L represents a leaving group and M represents...

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Bibliographische Detailangaben
Hauptverfasser:	VAN DER MADE, ALEXANDER, WILLEM, VAN GINKEL, ROELOF, DE WITH, JAN, EILENBERG, WOLF
Format:	Patent
Sprache:	ger
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	This invention relates to processes for making phosphorus compounds R 2 P-X-PR 2 , R 2 P-M, R 2 P-L and R 3 P, and the novel cation R 2 P + (L)-X-P + (L)R 2 , where R represents an optionally substituted hydrocarbyl group, X represents a bridging group, L represents a leaving group and M represents an alkali metal atom. The invention relates further to a process for making a compound R 2 P-L from a compound R-H via a new process for making the compound R-Li followed by its reaction with a compound Hal 2 P-L. The compound R 2 P-X-PR 2 is a ligand suitable for making catalysts for copolymerizing carbon monoxide and an olefinically unsaturated compound.