SCHALENKATALYSATOREN, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG
A shell catalyst (I) contains (A) one or more metals of Gp. VIII and/or IB on (B) a powder or formed support, these metals being in finely divided form within a shell ≤ 1200 (pref. not more than 100) nm thick, with crystallite sizes of ≤ 10 (pref. < 3) nm, in concns. of 0.05-35 wt.% w.r.t. dry wt...
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Zusammenfassung: | A shell catalyst (I) contains (A) one or more metals of Gp. VIII and/or IB on (B) a powder or formed support, these metals being in finely divided form within a shell ≤ 1200 (pref. not more than 100) nm thick, with crystallite sizes of ≤ 10 (pref. < 3) nm, in concns. of 0.05-35 wt.% w.r.t. dry wt. of catalyst. Also claimed is (i) a process for the prodn. of (I) by coating the support with aq. solns. of ≥ 1 preformed, mono- or bi-metallic colloids of the above catalyst metals, stabilised with strongly hydrophilic surfactants; (ii) an electro-catalyst contg Gp. VIII metal(s) on a conductive support, obtd. by coating the support as above. |
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