VERFAHREN ZUM ERZEUGEN VON C3- UND C4- OLEFINEN AUS EINEM C4- BIS C7-OLEFINE ENTHALTENDEN EINSATZGEMISCH

Production of 3-4 olefins from a mixture containing 4-7C olefins comprises: (a) vaporising the mixture and mixing with water vapour, where wt. ratio of H2O:hydrocarbons is 0.5-3:1; (b) feeding the mixture containing the water vapour into a reactor at 380-700 degC containing a granular form-selective...

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Bibliographische Detailangaben
Hauptverfasser:	KOENIG, PETER, HIGMAN, CHRISTOPHER, MOELLER, FRIEDRICH-WILHELM, HOLTMANN, HANS-DIETER
Format:	Patent
Sprache:	ger
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS CHEMISTRY CRACKING HYDROCARBON OILS FUELS LUBRICANTS METALLURGY MINERAL WAXES ORGANIC CHEMISTRY PEAT PETROLEUM, GAS OR COKE INDUSTRIES PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE
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Beschreibung
Zusammenfassung:	Production of 3-4 olefins from a mixture containing 4-7C olefins comprises: (a) vaporising the mixture and mixing with water vapour, where wt. ratio of H2O:hydrocarbons is 0.5-3:1; (b) feeding the mixture containing the water vapour into a reactor at 380-700 degC containing a granular form-selective zeolite catalyst (pentasil type) having an atomic ratio Si:Al of 10-200:1; and (c) withdrawing a product mixture from the reactor whose temperature is 20-80 degC lower than the starting temperature and whose total content of propylene and butene isomers is at least 60 wt.% of the olefinic components of the starting mixture.