Comparative Studies on MG49-LiClO4and MG49-TiO2-SiO2-LiClO4Polymer Electrolytes

MG49-LiClO4 and MG49-TiO2-SiO2-LiClO4 polymer electrolytes were prepared through solution-cast technique. In the present case, MG49-LiClO4 and MG49-TiO2-SiO2-LiClO4 polymer electrolytes were subjected to structural, electrochemical, and some other relevant analyses. MG49-LiClO4 and MG49-TiO2-SiO2-LiClO4 polymer electrolytes had exhibited hierarchical structure changes upon different salt-loaded levels. MG49-LiClO4 and MG49-TiO2-SiO2-LiClO4 polymer electrolytes had achieved maximum ionic conductivities at 25 wt.% salt-loaded level. In comparison, MG49-LiClO4 and MG49-TiO2-SiO2-LiClO4 polymer electrolytes had demonstrated distinct transport mechanisms in a similar experimental configuration. MG49-LiClO4 and MG49-TiO2-SiO2-LiClO4 polymer electrolytes had exhibited different stability characteristics over a certain operational range.