Difluorination ability of F-TEDA-BF 4 in the transannular cyclization of bicyclo[3.3.1]nonane dienes in monoglyme

Difluorination ability of F-TEDA-BF 4 in the transannular cyclization of bicyclo[3.3.1]nonane dienes in monoglyme

The interaction of 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (F-TEDA-BF 4) with 3,7-bismethylenebicyclo[3.3.1]nonane and its derivatives in monoglyme results in the transannular cyclization of the dienes to form 1-fluoro-3-fluoroalkyladamantanes.

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Veröffentlicht in:Mendeleev communications 2002, Vol.12 (1), p.23-24
Hauptverfasser: Serguchev, Yurii A., Lourie, Lyudmila F., Ponomarenko, Maxim V.
Format: Artikel
Sprache:eng
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Zusammenfassung:The interaction of 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (F-TEDA-BF 4) with 3,7-bismethylenebicyclo[3.3.1]nonane and its derivatives in monoglyme results in the transannular cyclization of the dienes to form 1-fluoro-3-fluoroalkyladamantanes.
ISSN:0959-9436
DOI:10.1070/MC2002v012n01ABEH001531