Superelectrophiles generated in mBr2nAlBr3 systems

Superelectrophiles generated in mBr2nAlBr3 systems

MNDO/PM3 calculations have proved the possibility of the existence in mBr2nAlBr3 systems of highly electrophilic complexes with bidentate coordination of AlBr4-anions with a positively charged (up to + 1.45 a.u.) Br atom.

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Veröffentlicht in:Mendeleev communications 1996, Vol.6 (5), p.175-178
Hauptverfasser: Chistyakov, Anatolii L., Stankevich, Ivan V., Akhrem, Irena S., Gambaryan, Nina P., Vol’pin, Mark E.
Format: Artikel
Sprache:eng
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Zusammenfassung:MNDO/PM3 calculations have proved the possibility of the existence in mBr2nAlBr3 systems of highly electrophilic complexes with bidentate coordination of AlBr4-anions with a positively charged (up to + 1.45 a.u.) Br atom.
ISSN:0959-9436
DOI:10.1070/MC1996v006n05ABEH000632