Metal Complexes of Porphyrin Dimers with Ether and CC Bonds

Metal Complexes of Porphyrin Dimers with Ether and CC Bonds

A novel synthesis of a heterometallic complex of ether-bonded porphyrin–chlorin has been performed; metal complexes of α-hydroxyethyl-substituted porphyrins were found to form 2,3-bis-metallporphyrinbut-2-enes in the presence of trifluoroacetic acid; the dimers of two different types exhibited essen...

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Veröffentlicht in:Mendeleev communications 1995, Vol.5 (2), p.44-46
Hauptverfasser: Levinson, Ekaterina G., Reztsova, Natalia A., Mironov, Andrei F.
Format: Artikel
Sprache:eng
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Zusammenfassung:A novel synthesis of a heterometallic complex of ether-bonded porphyrin–chlorin has been performed; metal complexes of α-hydroxyethyl-substituted porphyrins were found to form 2,3-bis-metallporphyrinbut-2-enes in the presence of trifluoroacetic acid; the dimers of two different types exhibited essentially distinct fragmentation in plasma desorption mass spectrometry (PDMS).
ISSN:0959-9436
DOI:10.1070/MC1995v005n02ABEH000450