1,2- and 1,4-Addition Reactions of α-Metallated η 6-Alkylarene)tricarbonylchromium Complexes to Carbonyl Compounds

1,2- and 1,4-Addition Reactions of α-Metallated η 6-Alkylarene)tricarbonylchromium Complexes to Carbonyl Compounds

A [η 6-benzylcopper(I)]tricarbonylchromium complex has been obtained and its 1,4-addition reaction with methyl vinyl ketone carried out, while a convenient method for the 1,2-addition of benzyllithium derivatives of (η 6-alkylarene)tricarbonylchromium complexes to carbonyl compounds has been elabora...

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Veröffentlicht in:Mendeleev communications 1993, Vol.3 (2), p.43-45
Hauptverfasser: Kalinin, Valery N., Cherepanov, ll’ya A., Moiseev, Sergey K.
Format: Artikel
Sprache:eng
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Zusammenfassung:A [η 6-benzylcopper(I)]tricarbonylchromium complex has been obtained and its 1,4-addition reaction with methyl vinyl ketone carried out, while a convenient method for the 1,2-addition of benzyllithium derivatives of (η 6-alkylarene)tricarbonylchromium complexes to carbonyl compounds has been elaborated.
ISSN:0959-9436
DOI:10.1070/MC1993v003n02ABEH000213