The ν 9 Band of Propyne- d3
A high-resolution Fourier transform spectrum of the ν 9 band of CD 3CCH has been recorded at an apodized resolution of 0.004 cm−1 and analyzed. More than 1700 lines in the spectrum have been assigned and the parameters of the ν 9 state derived. The standard deviation of the fit was 0.00034 cm −1. In...
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Veröffentlicht in: | Journal of molecular spectroscopy 1993, Vol.160 (2), p.502-511 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | A high-resolution Fourier transform spectrum of the ν
9 band of CD
3CCH has been recorded at an apodized resolution of 0.004 cm−1 and analyzed. More than 1700 lines in the spectrum have been assigned and the parameters of the ν
9 state derived. The standard deviation of the fit was 0.00034 cm
−1. In order to achieve this fit it was necessary to include
l-type doubling interaction and Fermi resonance between ν
9 and the
E component of 2ν
10. |
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ISSN: | 0022-2852 1096-083X |
DOI: | 10.1006/jmsp.1993.1196 |