The ν 9 Band of Propyne- d3

A high-resolution Fourier transform spectrum of the ν 9 band of CD 3CCH has been recorded at an apodized resolution of 0.004 cm−1 and analyzed. More than 1700 lines in the spectrum have been assigned and the parameters of the ν 9 state derived. The standard deviation of the fit was 0.00034 cm −1. In...

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Veröffentlicht in:Journal of molecular spectroscopy 1993, Vol.160 (2), p.502-511
Hauptverfasser: Sule, N.S., Kshirsagar, R.J., Job, V.A.
Format: Artikel
Sprache:eng
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Zusammenfassung:A high-resolution Fourier transform spectrum of the ν 9 band of CD 3CCH has been recorded at an apodized resolution of 0.004 cm−1 and analyzed. More than 1700 lines in the spectrum have been assigned and the parameters of the ν 9 state derived. The standard deviation of the fit was 0.00034 cm −1. In order to achieve this fit it was necessary to include l-type doubling interaction and Fermi resonance between ν 9 and the E component of 2ν 10.
ISSN:0022-2852
1096-083X
DOI:10.1006/jmsp.1993.1196