Thermochemical Properties, Reaction Paths and Kinetic Mechanism for Sulfur-Chloro Hydrocarbon Combustion: Part I: Thermochemistry and Pyrolysis of Chlorosulfides

Almost no data exists in the literature on thermochemical properties enthalpy of formation, entropy or heat capacities for chlorinated sulfur hydrocarbons and oxygenated intermediates in atmospheric or thermal oxidation reactions. Even less kinetic data exists on the elementary processes involved in...

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Bibliographische Detailangaben
Hauptverfasser:	Montgomery, Christopher J, Bockelie, Michael J, Sarofim, Adel F, Lee, Jongwoo, Bozzelli, Joseph W
Format:	Report
Sprache:	eng
Schlagworte:	ATMOSPHERIC CHEMISTRY CHLORINATED HYDROCARBONS CHLOROSULFIDES DATA BASES DOCUMENTS ENTHALPY ENTROPY ETHYL RADICALS HEAT Inorganic Chemistry KINETICS Organic Chemistry OXIDATION OXIDATION REDUCTION REACTIONS PATHS PYROLYSIS REACTION CONTROL SYSTEMS REACTION KINETICS SULFIDES SULFUR THERMOCHEMISTRY Thermodynamics
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Beschreibung
Zusammenfassung:	Almost no data exists in the literature on thermochemical properties enthalpy of formation, entropy or heat capacities for chlorinated sulfur hydrocarbons and oxygenated intermediates in atmospheric or thermal oxidation reactions. Even less kinetic data exists on the elementary processes involved in these reaction systems. This study describes a first attempt to generate a thermochemical property data set and an elementary reaction mechanism for pyrolysis and oxidation of diethyl sulfide and dichloro-diethyl sulfide. The original document contains color images. Prepared in cooperation with New Jersey Institute of Technology, Newark, NJ.