Synthesis, Characterization and Explosive Properties of 3,5-Dinitro-2,4,6-Triaminopyridine and Its 1-Oxide
3,5-Dinitro-2,4,6-triaminopyridine was prepared by oxidative amination of 2-chloro-3,5- dinitropyridine or 2,6-diamino-3,5-dinitropyridine, or by treatment of the latter compound with hydroxylamine. 3,5-Dinitro-2,4,6-triaminopyridine-1 -oxide was prepared by oxidation of the parent heterocycle with...
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| creator | Merwin, Lawrence H Nissan, Robin A Wilson, William S Gilardi, Richard D |
| description | 3,5-Dinitro-2,4,6-triaminopyridine was prepared by oxidative amination of 2-chloro-3,5- dinitropyridine or 2,6-diamino-3,5-dinitropyridine, or by treatment of the latter compound with hydroxylamine. 3,5-Dinitro-2,4,6-triaminopyridine-1 -oxide was prepared by oxidation of the parent heterocycle with hydrogen peroxide, or by treatment of 2,6-diamino-3,5-dinitropyridine-1 - oxide with hydroxylamine. This compound features intramolecular and intermolecular hydrogen bonding which results in high density, thermal stability, and insensitivity to impact. jg p.3 |
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This compound features intramolecular and intermolecular hydrogen bonding which results in high density, thermal stability, and insensitivity to impact. jg p.3</description><language>eng</language><subject>2-CHLORO-3 ; 5-DINITROPYRIDINE ; AMINATION ; AMINES ; Ammunition and Explosives ; CHEMICAL BONDS ; DIAMINO-3 ; EXPLOSIVES ; HIGH DENSITY ; HYDROGEN PEROXIDE ; HYDROXYL RADICALS ; HYDROXYLAMINE ; IMPACT ; Inorganic Chemistry ; NITRO RADICALS ; Organic Chemistry ; ORGANIC COMPOUNDS ; OXIDATION ; OXIDES ; PE62633N ; Physical Chemistry ; PYRIDINES ; SENSITIVITY ; SYNTHESIS ; THERMAL STABILITY ; WU132120</subject><creationdate>1995</creationdate><rights>APPROVED FOR PUBLIC RELEASE</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,776,881,27544,27545</link.rule.ids><linktorsrc>$$Uhttps://apps.dtic.mil/sti/citations/ADA299641$$EView_record_in_DTIC$$FView_record_in_$$GDTIC$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Merwin, Lawrence H</creatorcontrib><creatorcontrib>Nissan, Robin A</creatorcontrib><creatorcontrib>Wilson, William S</creatorcontrib><creatorcontrib>Gilardi, Richard D</creatorcontrib><creatorcontrib>NAVAL AIR WARFARE CENTER WEAPONS DIV CHINA LAKE CA</creatorcontrib><title>Synthesis, Characterization and Explosive Properties of 3,5-Dinitro-2,4,6-Triaminopyridine and Its 1-Oxide</title><description>3,5-Dinitro-2,4,6-triaminopyridine was prepared by oxidative amination of 2-chloro-3,5- dinitropyridine or 2,6-diamino-3,5-dinitropyridine, or by treatment of the latter compound with hydroxylamine. 3,5-Dinitro-2,4,6-triaminopyridine-1 -oxide was prepared by oxidation of the parent heterocycle with hydrogen peroxide, or by treatment of 2,6-diamino-3,5-dinitropyridine-1 - oxide with hydroxylamine. This compound features intramolecular and intermolecular hydrogen bonding which results in high density, thermal stability, and insensitivity to impact. jg p.3</description><subject>2-CHLORO-3</subject><subject>5-DINITROPYRIDINE</subject><subject>AMINATION</subject><subject>AMINES</subject><subject>Ammunition and Explosives</subject><subject>CHEMICAL BONDS</subject><subject>DIAMINO-3</subject><subject>EXPLOSIVES</subject><subject>HIGH DENSITY</subject><subject>HYDROGEN PEROXIDE</subject><subject>HYDROXYL RADICALS</subject><subject>HYDROXYLAMINE</subject><subject>IMPACT</subject><subject>Inorganic Chemistry</subject><subject>NITRO RADICALS</subject><subject>Organic Chemistry</subject><subject>ORGANIC COMPOUNDS</subject><subject>OXIDATION</subject><subject>OXIDES</subject><subject>PE62633N</subject><subject>Physical Chemistry</subject><subject>PYRIDINES</subject><subject>SENSITIVITY</subject><subject>SYNTHESIS</subject><subject>THERMAL STABILITY</subject><subject>WU132120</subject><fulltext>true</fulltext><rsrctype>report</rsrctype><creationdate>1995</creationdate><recordtype>report</recordtype><sourceid>1RU</sourceid><recordid>eNqFy70KwjAUQOEuDqK-gUMeIBn6Y6FjaSs6Kdi9hOaWXqlJuLlI69Mr4u50hsO3ju63xfIIAYMU1ahJ9wyEL83orNDWiGb2kwv4BHEl54EYIQg3iFQeVI0WmZxKZCZz1RLqB1rnF0KDFr78zEHE6jKjgW20GvQUYPfrJtofm7Y6KcPYd4E_hLuyLpOiyLM4_bPfUOA8aQ</recordid><startdate>199509</startdate><enddate>199509</enddate><creator>Merwin, Lawrence H</creator><creator>Nissan, Robin A</creator><creator>Wilson, William S</creator><creator>Gilardi, Richard D</creator><scope>1RU</scope><scope>BHM</scope></search><sort><creationdate>199509</creationdate><title>Synthesis, Characterization and Explosive Properties of 3,5-Dinitro-2,4,6-Triaminopyridine and Its 1-Oxide</title><author>Merwin, Lawrence H ; Nissan, Robin A ; Wilson, William S ; Gilardi, Richard D</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-dtic_stinet_ADA2996413</frbrgroupid><rsrctype>reports</rsrctype><prefilter>reports</prefilter><language>eng</language><creationdate>1995</creationdate><topic>2-CHLORO-3</topic><topic>5-DINITROPYRIDINE</topic><topic>AMINATION</topic><topic>AMINES</topic><topic>Ammunition and Explosives</topic><topic>CHEMICAL BONDS</topic><topic>DIAMINO-3</topic><topic>EXPLOSIVES</topic><topic>HIGH DENSITY</topic><topic>HYDROGEN PEROXIDE</topic><topic>HYDROXYL RADICALS</topic><topic>HYDROXYLAMINE</topic><topic>IMPACT</topic><topic>Inorganic Chemistry</topic><topic>NITRO RADICALS</topic><topic>Organic Chemistry</topic><topic>ORGANIC COMPOUNDS</topic><topic>OXIDATION</topic><topic>OXIDES</topic><topic>PE62633N</topic><topic>Physical Chemistry</topic><topic>PYRIDINES</topic><topic>SENSITIVITY</topic><topic>SYNTHESIS</topic><topic>THERMAL STABILITY</topic><topic>WU132120</topic><toplevel>online_resources</toplevel><creatorcontrib>Merwin, Lawrence H</creatorcontrib><creatorcontrib>Nissan, Robin A</creatorcontrib><creatorcontrib>Wilson, William S</creatorcontrib><creatorcontrib>Gilardi, Richard D</creatorcontrib><creatorcontrib>NAVAL AIR WARFARE CENTER WEAPONS DIV CHINA LAKE CA</creatorcontrib><collection>DTIC Technical Reports</collection><collection>DTIC STINET</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Merwin, Lawrence H</au><au>Nissan, Robin A</au><au>Wilson, William S</au><au>Gilardi, Richard D</au><aucorp>NAVAL AIR WARFARE CENTER WEAPONS DIV CHINA LAKE CA</aucorp><format>book</format><genre>unknown</genre><ristype>RPRT</ristype><btitle>Synthesis, Characterization and Explosive Properties of 3,5-Dinitro-2,4,6-Triaminopyridine and Its 1-Oxide</btitle><date>1995-09</date><risdate>1995</risdate><abstract>3,5-Dinitro-2,4,6-triaminopyridine was prepared by oxidative amination of 2-chloro-3,5- dinitropyridine or 2,6-diamino-3,5-dinitropyridine, or by treatment of the latter compound with hydroxylamine. 3,5-Dinitro-2,4,6-triaminopyridine-1 -oxide was prepared by oxidation of the parent heterocycle with hydrogen peroxide, or by treatment of 2,6-diamino-3,5-dinitropyridine-1 - oxide with hydroxylamine. This compound features intramolecular and intermolecular hydrogen bonding which results in high density, thermal stability, and insensitivity to impact. jg p.3</abstract><oa>free_for_read</oa></addata></record> |
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| subjects | 2-CHLORO-3 5-DINITROPYRIDINE AMINATION AMINES Ammunition and Explosives CHEMICAL BONDS DIAMINO-3 EXPLOSIVES HIGH DENSITY HYDROGEN PEROXIDE HYDROXYL RADICALS HYDROXYLAMINE IMPACT Inorganic Chemistry NITRO RADICALS Organic Chemistry ORGANIC COMPOUNDS OXIDATION OXIDES PE62633N Physical Chemistry PYRIDINES SENSITIVITY SYNTHESIS THERMAL STABILITY WU132120 |
| title | Synthesis, Characterization and Explosive Properties of 3,5-Dinitro-2,4,6-Triaminopyridine and Its 1-Oxide |
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