Synthesis, Characterization and Explosive Properties of 3,5-Dinitro-2,4,6-Triaminopyridine and Its 1-Oxide

3,5-Dinitro-2,4,6-triaminopyridine was prepared by oxidative amination of 2-chloro-3,5- dinitropyridine or 2,6-diamino-3,5-dinitropyridine, or by treatment of the latter compound with hydroxylamine. 3,5-Dinitro-2,4,6-triaminopyridine-1 -oxide was prepared by oxidation of the parent heterocycle with...

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Bibliographische Detailangaben
Hauptverfasser:	Merwin, Lawrence H, Nissan, Robin A, Wilson, William S, Gilardi, Richard D
Format:	Report
Sprache:	eng
Schlagworte:	2-CHLORO-3 5-DINITROPYRIDINE AMINATION AMINES Ammunition and Explosives CHEMICAL BONDS DIAMINO-3 EXPLOSIVES HIGH DENSITY HYDROGEN PEROXIDE HYDROXYL RADICALS HYDROXYLAMINE IMPACT Inorganic Chemistry NITRO RADICALS Organic Chemistry ORGANIC COMPOUNDS OXIDATION OXIDES PE62633N Physical Chemistry PYRIDINES SENSITIVITY SYNTHESIS THERMAL STABILITY WU132120
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Zusammenfassung:	3,5-Dinitro-2,4,6-triaminopyridine was prepared by oxidative amination of 2-chloro-3,5- dinitropyridine or 2,6-diamino-3,5-dinitropyridine, or by treatment of the latter compound with hydroxylamine. 3,5-Dinitro-2,4,6-triaminopyridine-1 -oxide was prepared by oxidation of the parent heterocycle with hydrogen peroxide, or by treatment of 2,6-diamino-3,5-dinitropyridine-1 - oxide with hydroxylamine. This compound features intramolecular and intermolecular hydrogen bonding which results in high density, thermal stability, and insensitivity to impact. jg p.3