A Convenient Synthesis of Diaminoglyoxime and Diaminofurazan: Useful Precursors for the Synthesis of High Density Energetic Materials

The reaction of glyoxime (4) and hydroxylamine hydrochloride in aqueous sodium hydroxide was found to be a safe and inexpensive method for the preparation of multigram quantities of diaminoglyoxime (5). Potassium hydroxide mediated dehydration of 5 furnished diaminofurazan (1) in good yield of excep...

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Bibliographische Detailangaben
Hauptverfasser:	Gunasekaran, Ananthakrishnan, Jayachandran, Thiruvalam, Boyer, Joseph H, Trudell, Mark L
Format:	Report
Sprache:	eng
Schlagworte:	AMINES Ammunition and Explosives CARBON CHLORIDES COMPOSITE MATERIALS DIAMINOFURAZAN DIAMINOGLYOXIME ENERGETIC PROPERTIES FURAZAN GLYOXIMES HIGH DENSITY HYDROCHLORIDE HYDROGEN HYDROXYL RADICALS Inorganic Chemistry Laminates and Composite Materials MATERIALS METHANE MNOTO(METHANEDINITRAMINO-OXDIAZOL-TRIAZOLO-OXADIAZOLIUM) NITRAMINES NITROGEN Organic Chemistry OXADIAZOLES OXIMES OXYGEN POTASSIUM COMPOUNDS PURITY SODIUM HYDROXIDE SOLUTIONS(MIXTURES) SYNTHESIS
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Zusammenfassung:	The reaction of glyoxime (4) and hydroxylamine hydrochloride in aqueous sodium hydroxide was found to be a safe and inexpensive method for the preparation of multigram quantities of diaminoglyoxime (5). Potassium hydroxide mediated dehydration of 5 furnished diaminofurazan (1) in good yield of exceptional purity. The ready availability of 1 and 5 has facilitated the synthesis of new energetic furazan derivative MNOTO (B). jg