Silylated Tetrahydrofuran Derivatives
2-Trimethylsilyltetrahydrofuran and 2-(2-trimethylsilylethyl)tetrahydrofuran have been isolated from dechlorinations of mixtures of silane monomers by potassium metal in tetrahydrofuran solvent. These low yield products may involve the common intermediacy of the 2-tetrahydrofuryl anion or the 2-tetr...
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| creator | Schilling,Curtis L , Jr |
| description | 2-Trimethylsilyltetrahydrofuran and 2-(2-trimethylsilylethyl)tetrahydrofuran have been isolated from dechlorinations of mixtures of silane monomers by potassium metal in tetrahydrofuran solvent. These low yield products may involve the common intermediacy of the 2-tetrahydrofuryl anion or the 2-tetrahydrofuryl radical and its trapping by trimethylchlorosilane and vinyl-trimethylsilane. (Author) |
| format | Report |
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These low yield products may involve the common intermediacy of the 2-tetrahydrofuryl anion or the 2-tetrahydrofuryl radical and its trapping by trimethylchlorosilane and vinyl-trimethylsilane. (Author)</description><language>eng</language><subject>ANIONS ; CHEMICAL RADICALS ; CHLORINATION ; Dechlorination ; FURANS ; Hydrofuran ; HYDROGEN ; METHYL RADICALS ; Methylchlorosilane ; Organic Chemistry ; Plastics ; POTASSIUM ; REACTION KINETICS ; SILANES ; SILICON ; SOLVENTS</subject><creationdate>1982</creationdate><rights>APPROVED FOR PUBLIC RELEASE</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,776,881,27546,27547</link.rule.ids><linktorsrc>$$Uhttps://apps.dtic.mil/sti/citations/ADA122593$$EView_record_in_DTIC$$FView_record_in_$$GDTIC$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Schilling,Curtis L , Jr</creatorcontrib><creatorcontrib>UNION CARBIDE CORP TARRYTOWN NY</creatorcontrib><title>Silylated Tetrahydrofuran Derivatives</title><description>2-Trimethylsilyltetrahydrofuran and 2-(2-trimethylsilylethyl)tetrahydrofuran have been isolated from dechlorinations of mixtures of silane monomers by potassium metal in tetrahydrofuran solvent. These low yield products may involve the common intermediacy of the 2-tetrahydrofuryl anion or the 2-tetrahydrofuryl radical and its trapping by trimethylchlorosilane and vinyl-trimethylsilane. (Author)</description><subject>ANIONS</subject><subject>CHEMICAL RADICALS</subject><subject>CHLORINATION</subject><subject>Dechlorination</subject><subject>FURANS</subject><subject>Hydrofuran</subject><subject>HYDROGEN</subject><subject>METHYL RADICALS</subject><subject>Methylchlorosilane</subject><subject>Organic Chemistry</subject><subject>Plastics</subject><subject>POTASSIUM</subject><subject>REACTION KINETICS</subject><subject>SILANES</subject><subject>SILICON</subject><subject>SOLVENTS</subject><fulltext>true</fulltext><rsrctype>report</rsrctype><creationdate>1982</creationdate><recordtype>report</recordtype><sourceid>1RU</sourceid><recordid>eNrjZFANzsypzEksSU1RCEktKUrMqEwpyk8rLUrMU3BJLcosSyzJLEst5mFgTUvMKU7lhdLcDDJuriHOHropJZnJ8cUlmXmpJfGOLo6GRkamlsbGBKQB9FQk5w</recordid><startdate>19821203</startdate><enddate>19821203</enddate><creator>Schilling,Curtis L , Jr</creator><scope>1RU</scope><scope>BHM</scope></search><sort><creationdate>19821203</creationdate><title>Silylated Tetrahydrofuran Derivatives</title><author>Schilling,Curtis L , Jr</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-dtic_stinet_ADA1225933</frbrgroupid><rsrctype>reports</rsrctype><prefilter>reports</prefilter><language>eng</language><creationdate>1982</creationdate><topic>ANIONS</topic><topic>CHEMICAL RADICALS</topic><topic>CHLORINATION</topic><topic>Dechlorination</topic><topic>FURANS</topic><topic>Hydrofuran</topic><topic>HYDROGEN</topic><topic>METHYL RADICALS</topic><topic>Methylchlorosilane</topic><topic>Organic Chemistry</topic><topic>Plastics</topic><topic>POTASSIUM</topic><topic>REACTION KINETICS</topic><topic>SILANES</topic><topic>SILICON</topic><topic>SOLVENTS</topic><toplevel>online_resources</toplevel><creatorcontrib>Schilling,Curtis L , Jr</creatorcontrib><creatorcontrib>UNION CARBIDE CORP TARRYTOWN NY</creatorcontrib><collection>DTIC Technical Reports</collection><collection>DTIC STINET</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Schilling,Curtis L , Jr</au><aucorp>UNION CARBIDE CORP TARRYTOWN NY</aucorp><format>book</format><genre>unknown</genre><ristype>RPRT</ristype><btitle>Silylated Tetrahydrofuran Derivatives</btitle><date>1982-12-03</date><risdate>1982</risdate><abstract>2-Trimethylsilyltetrahydrofuran and 2-(2-trimethylsilylethyl)tetrahydrofuran have been isolated from dechlorinations of mixtures of silane monomers by potassium metal in tetrahydrofuran solvent. These low yield products may involve the common intermediacy of the 2-tetrahydrofuryl anion or the 2-tetrahydrofuryl radical and its trapping by trimethylchlorosilane and vinyl-trimethylsilane. (Author)</abstract><oa>free_for_read</oa></addata></record> |
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| language | eng |
| recordid | cdi_dtic_stinet_ADA122593 |
| source | DTIC Technical Reports |
| subjects | ANIONS CHEMICAL RADICALS CHLORINATION Dechlorination FURANS Hydrofuran HYDROGEN METHYL RADICALS Methylchlorosilane Organic Chemistry Plastics POTASSIUM REACTION KINETICS SILANES SILICON SOLVENTS |
| title | Silylated Tetrahydrofuran Derivatives |
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