Silylated Tetrahydrofuran Derivatives
2-Trimethylsilyltetrahydrofuran and 2-(2-trimethylsilylethyl)tetrahydrofuran have been isolated from dechlorinations of mixtures of silane monomers by potassium metal in tetrahydrofuran solvent. These low yield products may involve the common intermediacy of the 2-tetrahydrofuryl anion or the 2-tetr...
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| Zusammenfassung: | 2-Trimethylsilyltetrahydrofuran and 2-(2-trimethylsilylethyl)tetrahydrofuran have been isolated from dechlorinations of mixtures of silane monomers by potassium metal in tetrahydrofuran solvent. These low yield products may involve the common intermediacy of the 2-tetrahydrofuryl anion or the 2-tetrahydrofuryl radical and its trapping by trimethylchlorosilane and vinyl-trimethylsilane. (Author) |
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