Synthesis, X-Ray Crystal Structure and Reactions of (closo-1,3-mu-2,3-mu(1,2-mu (eta2-3,4-CH2CH2C(CH3) =CHCH2CH2CH2)) -3-H-3-PPh3-3,1,2-RhC2 B9H9), a Metallocarbaborane Catalyst

Synthesis, X-Ray Crystal Structure and Reactions of (closo-1,3-mu-2,3-mu(1,2-mu (eta2-3,4-CH2CH2C(CH3) =CHCH2CH2CH2)) -3-H-3-PPh3-3,1,2-RhC2 B9H9), a Metallocarbaborane Catalyst

The synthesis, X-ray crystal structure of the title compound and the initial rates of some alkene hydrogenations catalysed by this compound are reported.

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Bibliographische Detailangaben
Hauptverfasser: Delaney,Mark S, Teller,Raymond G, Hawthorne,M Frederick
Format: Report
Sprache:eng
Schlagworte:
ALKENES
Atomic and Molecular Physics and Spectroscopy
CARBORANES
CATALYSIS
CATALYSTS
CRYSTAL STRUCTURE
HYDROGENATION
Organic Chemistry
ORGANOMETALLIC COMPOUNDS
REACTION KINETICS
RHODIUM
SYNTHESIS(CHEMISTRY)
WUNR053608
X RAY SPECTRA
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Zusammenfassung:The synthesis, X-ray crystal structure of the title compound and the initial rates of some alkene hydrogenations catalysed by this compound are reported.