Efficient Peroxyloxalate Chemiluminescence from Reactions of N-Trifluoromethylsulfonyl Oxamides with Hydrogen Peroxide and Fluorescers

A new highly efficient class of chemiluminescent oxalic acid derivatives, N-trifluoromethyl sulfonyl oxamides, has been discovered. One member of this class, N,N'-bis(2,4,5-trichlorophenyl)-N,N'-bis(trifluoromethylsulfonyl) oxamide, has given the highest chemiluminescence quantum yield (34...

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Hauptverfasser:	Tseng,Shin-Shyong, Mohan,Arthur G, Haines,Linda G, Vizcarra,Lourdes S, Rauhut,Michael M
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Sprache:	eng
Schlagworte:	CHEMICAL DERIVATIVES CHEMILUMINESCENCE CHLORINE COMPOUNDS FLUORINE COMPOUNDS HYDROGEN PEROXIDE Organic Chemistry ORGANIC SOLVENTS OXAMIDES Physical Chemistry QUANTUM CHEMISTRY Quantum Theory and Relativity SULFONYL RADICALS Trifyl oxamide WUNR051668
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creator	Tseng,Shin-Shyong Mohan,Arthur G Haines,Linda G Vizcarra,Lourdes S Rauhut,Michael M
description	A new highly efficient class of chemiluminescent oxalic acid derivatives, N-trifluoromethyl sulfonyl oxamides, has been discovered. One member of this class, N,N'-bis(2,4,5-trichlorophenyl)-N,N'-bis(trifluoromethylsulfonyl) oxamide, has given the highest chemiluminescence quantum yield (34%) reported for a chemiluminescent reaction in an organic solvent system. (Author)
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One member of this class, N,N'-bis(2,4,5-trichlorophenyl)-N,N'-bis(trifluoromethylsulfonyl) oxamide, has given the highest chemiluminescence quantum yield (34%) reported for a chemiluminescent reaction in an organic solvent system. 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subjects	CHEMICAL DERIVATIVES CHEMILUMINESCENCE CHLORINE COMPOUNDS FLUORINE COMPOUNDS HYDROGEN PEROXIDE Organic Chemistry ORGANIC SOLVENTS OXAMIDES Physical Chemistry QUANTUM CHEMISTRY Quantum Theory and Relativity SULFONYL RADICALS Trifyl oxamide WUNR051668
title	Efficient Peroxyloxalate Chemiluminescence from Reactions of N-Trifluoromethylsulfonyl Oxamides with Hydrogen Peroxide and Fluorescers
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