Efficient Peroxyloxalate Chemiluminescence from Reactions of N-Trifluoromethylsulfonyl Oxamides with Hydrogen Peroxide and Fluorescers

Efficient Peroxyloxalate Chemiluminescence from Reactions of N-Trifluoromethylsulfonyl Oxamides with Hydrogen Peroxide and Fluorescers

A new highly efficient class of chemiluminescent oxalic acid derivatives, N-trifluoromethyl sulfonyl oxamides, has been discovered. One member of this class, N,N'-bis(2,4,5-trichlorophenyl)-N,N'-bis(trifluoromethylsulfonyl) oxamide, has given the highest chemiluminescence quantum yield (34...

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Bibliographische Detailangaben
Hauptverfasser: Tseng,Shin-Shyong, Mohan,Arthur G, Haines,Linda G, Vizcarra,Lourdes S, Rauhut,Michael M
Format: Report
Sprache:eng
Schlagworte:
CHEMICAL DERIVATIVES
CHEMILUMINESCENCE
CHLORINE COMPOUNDS
FLUORINE COMPOUNDS
HYDROGEN PEROXIDE
Organic Chemistry
ORGANIC SOLVENTS
OXAMIDES
Physical Chemistry
QUANTUM CHEMISTRY
Quantum Theory and Relativity
SULFONYL RADICALS
Trifyl oxamide
WUNR051668
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Beschreibung
Zusammenfassung:A new highly efficient class of chemiluminescent oxalic acid derivatives, N-trifluoromethyl sulfonyl oxamides, has been discovered. One member of this class, N,N'-bis(2,4,5-trichlorophenyl)-N,N'-bis(trifluoromethylsulfonyl) oxamide, has given the highest chemiluminescence quantum yield (34%) reported for a chemiluminescent reaction in an organic solvent system. (Author)