A Homogeneous Metallocarborane Catalyst, 3,3-(PPh3)2-3-H-3,1,2-RhC2B9H11

C38H42B9P2Rh, monoclinic, P2 (sub 1)/n, a=12.669(6), b=18.587(4), c=16.041(7) A, beta=97.08(4) degrees, Z=4, D sub m=1.29(2)(flotation), D=1.294 g/cc. The Rh(III) ion is complexed by one terminal hydride, one pi-B9C2H11(2-) and two triphenylphosphine ligands. (Author) Supersedes AD-A025 007.

Gespeichert in:

Bibliographische Detailangaben
Hauptverfasser:	Hardy,Gordon E, Callahan,Kenneth P, Strouse,Charles E, Hawthorne,M Frederick
Format:	Report
Sprache:	eng
Schlagworte:	Atomic and Molecular Physics and Spectroscopy CARBORANES CATALYSTS CRYSTAL STRUCTURE Crystallography MOLECULAR STRUCTURE Organic Chemistry ORGANOMETALLIC COMPOUNDS PHENYL RADICALS PHOSPHINE RHODIUM COMPOUNDS SINGLE CRYSTALS X RAY DIFFRACTION
Online-Zugang:	Volltext bestellen
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	C38H42B9P2Rh, monoclinic, P2 (sub 1)/n, a=12.669(6), b=18.587(4), c=16.041(7) A, beta=97.08(4) degrees, Z=4, D sub m=1.29(2)(flotation), D=1.294 g/cc. The Rh(III) ion is complexed by one terminal hydride, one pi-B9C2H11(2-) and two triphenylphosphine ligands. (Author) Supersedes AD-A025 007.