Constitutive Equations for Polymer Solutions Derived from the Bead/Spring Model of Rouse and Zimm

Constitutive Equations for Polymer Solutions Derived from the Bead/Spring Model of Rouse and Zimm

Constitutive equations are derived for the Rouse/Zimm model without restriction on the number of springs per molecule or on the strength of bead-bread hydrodynamic interaction. The equations are of the same form as the constitutive equations for a network model, but the memory function is determined...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Lodge,A. S, Wu,Yeen-jing
Format: Report
Sprache:eng
Schlagworte:
MATHEMATICAL ANALYSIS
MATRICES(MATHEMATICS)
Physical Chemistry
POLYMERS
RELAXATION TIME
RHEOLOGY
SOLUTIONS(MIXTURES)
VISCOELASTICITY
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Beschreibung
Zusammenfassung:Constitutive equations are derived for the Rouse/Zimm model without restriction on the number of springs per molecule or on the strength of bead-bread hydrodynamic interaction. The equations are of the same form as the constitutive equations for a network model, but the memory function is determined to within three arbitrary constants. (Author)