THE REFINEMENT OF THE CRYSTAL STRUCTURE OF NORBORNADIENE PALLADIUM CHLORIDE

THE REFINEMENT OF THE CRYSTAL STRUCTURE OF NORBORNADIENE PALLADIUM CHLORIDE

The crystal structure of norbornadiene palladium chloride has been refined with data obtained by counter methods from crystals maintained at liquid nitrogen temperature. After refinement the conventional discrepancy index R=0.0275. The carbon-carbon single bond distances in the norbornadiene molecul...

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Bibliographische Detailangaben
Hauptverfasser: BAENZIGER,N C, Richards,G F, Doyle,J R
Format: Report
Sprache:eng
Schlagworte:
CHLORIDES
CRYOGENICS
CRYSTAL STRUCTURE
NORBORNADIENES
ORGANOMETALLIC COMPOUNDS
PALLADIUM COMPOUNDS
SYMMETRY(CRYSTALLOGRAPHY)
TERPENES
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Zusammenfassung:The crystal structure of norbornadiene palladium chloride has been refined with data obtained by counter methods from crystals maintained at liquid nitrogen temperature. After refinement the conventional discrepancy index R=0.0275. The carbon-carbon single bond distances in the norbornadiene molecule are normal: 1.547, 1.552, 1.554 (=0.006) A; the double bond distances are barely significantly longer than normal: 1.366, 1.366 (=0.010) A. The observed double bond distance is now compatible with the infrared spectrum of the complexed olefin. (Author) Pub. in Acta Crystallographica v18 pt5 p924-6 1965(Copies available only to DDC users).