ELECTROCHEMICAL STUDIES IN THE SYNTHESIS OF N-F COMPOUNDS

ELECTROCHEMICAL STUDIES IN THE SYNTHESIS OF N-F COMPOUNDS

The goal of the work is to determine the mechanism by which electrochemical fluorination of ammonium and hydrazinium salts occur in anhydrous hydrogen fluoride (AHF). A major portion of the work to date was done to (1) develop a suitable reference electrode, (2) construct an HF handling system for p...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Spears, Larry G, Fiel, Larry D, Harrell, Wallace E ,Jr, Northrup, Margaret H
Format: Report
Sprache:eng
Schlagworte:
AMMONIUM COMPOUNDS
AMMONIUM FLUORIDE
COPPER ALLOYS
CORROSION
CORROSION RESISTANT ALLOYS
ELECTROCHEMISTRY
ELECTRODES
FLUORIDES
FLUORINATION
HYDROGEN
HYDROGEN COMPOUNDS
Inorganic Chemistry
LABORATORY EQUIPMENT
MONEL METAL 400
NICKEL ALLOYS
OXIDIZERS
SYNTHESIS(CHEMISTRY)
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Beschreibung
Zusammenfassung:The goal of the work is to determine the mechanism by which electrochemical fluorination of ammonium and hydrazinium salts occur in anhydrous hydrogen fluoride (AHF). A major portion of the work to date was done to (1) develop a suitable reference electrode, (2) construct an HF handling system for preparing and maintaining AHF at low electrical conductivities, and (3) select a suitable working electrode. The Hg/Hg2F2 electrode satisfies the requirements for a reference electrode, and Monel (alloy 400) satisfies the requirements for a working electrode. Monel is now being used as an anode and Hg/Hg2F2 as a reference electrode in studying the electrolysis of NH4F in AHF. See also AD609959.