Ionic Fluorine Chemistry

This report describes further attempts to prepare the ClF6 anion. The use of large excesses (up to ClF5:CsF of 120:1) or the use of activated CsF did not result in products containing the desired anion. Conflicting reports have appeared in the literature concerning the existence of a NOF-ClF5 adduct...

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Bibliographische Detailangaben
Hauptverfasser:	Hyde,Gene A, Mangold,Donald J
Format:	Report
Sprache:	eng
Schlagworte:	ACETONES ADDITION REACTIONS CESIUM COMPOUNDS CESIUM FLUORIDE CHLORATES CHLORIDES CHLORINE COMPOUNDS CHLORINE MONOFLUORIDE CHLORINE PENTAFLUORIDE CHLORINE TRIFLUORIDE COMPLEX COMPOUNDS FLUORIDES FLUORINE COMPOUNDS GAS CHROMATOGRAPHY HALOGEN COMPOUNDS HYDROLYSIS (U) SOLID ROCKET OXIDIZERS INTERHALOGEN OXIDIZERS IONS LIQUID ROCKET OXIDIZERS Liquid Rocket Propellants NITROSO COMPOUNDS NITROSYL FLUORIDE PARTICLE SIZE REACTION KINETICS Solid Rocket Propellants SOLUBILITY SYNTHESIS(CHEMISTRY) VAPOR PRESSURE
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Beschreibung
Zusammenfassung:	This report describes further attempts to prepare the ClF6 anion. The use of large excesses (up to ClF5:CsF of 120:1) or the use of activated CsF did not result in products containing the desired anion. Conflicting reports have appeared in the literature concerning the existence of a NOF-ClF5 adduct formed at -78 degrees. An investigation of this system showed that, while mixtures of NOF and ClF5 show a negative deviation from Raoult's Law, no solid product is formed. (Author)