ELECTROCHEMICAL STUDIES IN THE SYNTHESIS OF N-F COMPOUNDS

This report describes work which has been devoted to the development of a suitable working electrode for use in electrochemical fluorination studies in anhydrous HF (AHF). Investigations of possible working electrodes have involved antimony, bismuth, silver, aluminum, titanium, cobalt, iron, and mon...

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Bibliographische Detailangaben
Hauptverfasser:	Spears, Larry G, Fiel, Larry D, Harrell, Jr , Wallace E, Schmid, Gerhard M
Format:	Report
Sprache:	eng
Schlagworte:	ALUMINUM AMMONIA AMMONIUM COMPOUNDS ANODES(ELECTROLYTIC CELL) ANTIMONY BISMUTH COBALT COPPER CORROSION Electrochemical Energy Storage ELECTROCHEMISTRY ELECTRODES FLUORIDES FLUORINATION FLUORINE COMPOUNDS HALOCARBON PLASTICS HYDRAZINES HYDROGEN HYDROGEN COMPOUNDS Inorganic Chemistry IRON MATERIALS METALS MONEL METAL NICKEL ALLOYS NITROGEN COMPOUNDS POLARIZATION SILVER SYNTHESIS(CHEMISTRY)
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Beschreibung
Zusammenfassung:	This report describes work which has been devoted to the development of a suitable working electrode for use in electrochemical fluorination studies in anhydrous HF (AHF). Investigations of possible working electrodes have involved antimony, bismuth, silver, aluminum, titanium, cobalt, iron, and monel. Antimony, bismuth, and silver show a high anodic dissolution rate in AHF, while the other metals studied show passive behavior. Of the latter metals only monel formed a protective coating which permitted appreciable fluorine evolution to occur.