PROPULSION RESEARCH PROGRAM. HYDRIDE AND FLUORIDE INVESTIGATIONS

The complex formed between sulfur tetrafluoride and tetramethyl ammonium fluoride has been almost completely characterized. The compound believed to be (CH3)4N plus SF5- is stable to 70 to 100 C and reacts with water, nitrobenzene, formamide, and monomethyl formamide. The flourine nuclear magnetic r...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Hauptverfasser:	TUNDER, R, GIBBINS, S G, BREISACHER, P, SIEGAL, B, SHIELER, L
Format:	Report
Sprache:	eng
Schlagworte:	COMPOSITE MATERIALS DECABORANES FLUORIDES FORMAMIDES GRIGNARD REAGENTS HYDRIDES IONS MASS SPECTROSCOPY METHYL RADICALS NITRO RADICALS NITROBENZENES NUCLEAR MAGNETIC RESONANCE SILICON COMPOUNDS Solid Rocket Propellants SULFUR COMPOUNDS
Online-Zugang:	Volltext bestellen
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	The complex formed between sulfur tetrafluoride and tetramethyl ammonium fluoride has been almost completely characterized. The compound believed to be (CH3)4N plus SF5- is stable to 70 to 100 C and reacts with water, nitrobenzene, formamide, and monomethyl formamide. The flourine nuclear magnetic resonance spectrum of the compound exhibits a single line quite different from that of F- or SF4. The reaction between ferric chloride, phenyl magnesium bromide and hydrogen to form iron hydrides was studied. The products have been separated into at least five separate solid components based on differential solubility in various basic solvents.