catena-Poly[[bis-(dimethyl-formamide-κO)cadmium]-bis-(μ-4-nitro-phenyl-cyanamido-κN:N)]
In the title coordination polymer, [Cd(C(7)H(4)N(3)O(2))(2)(C(3)H(7)NO)(2)](n), the Cd(II) atom, lying on an inversion center, is six-coordinated in a distorted N(4)O(2) octa-hedral geometry. The N atoms of the 4-nitrophenylcyanamide anions form the equatorial plane and the O atoms of the dimethyl-f...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-03, Vol.68 (Pt 3), p.m232-m232 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In the title coordination polymer, [Cd(C(7)H(4)N(3)O(2))(2)(C(3)H(7)NO)(2)](n), the Cd(II) atom, lying on an inversion center, is six-coordinated in a distorted N(4)O(2) octa-hedral geometry. The N atoms of the 4-nitrophenylcyanamide anions form the equatorial plane and the O atoms of the dimethyl-formamide mol-ecules occupy the axial positions. The anions act as bridging ligands, connecting the Cd atoms into a one-dimensional coordination polymer along [100]. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536812001924 |