Self-replicating Reverse Micelles

Conditions are described, under which the hydrolysis of octyl octanoate (O-OA) takes place at the interface of reverse micelles fanned by sodium octanoate (OA) in isooctane. Since the micelle-mediated hydrolysis affords fresh OA, which spontaneously assemble into new micelles, the reaction can be se...

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Veröffentlicht in:Chimia 1991-09, Vol.45 (9)
Hauptverfasser: Pascale Angelica Bachmann, Pier Luigi Luisi, Jacques Lang
Format: Artikel
Sprache:ger
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Zusammenfassung:Conditions are described, under which the hydrolysis of octyl octanoate (O-OA) takes place at the interface of reverse micelles fanned by sodium octanoate (OA) in isooctane. Since the micelle-mediated hydrolysis affords fresh OA, which spontaneously assemble into new micelles, the reaction can be seen as a self-replicating process. The kinetics and the spectroscopy of this self-replication process are presented.
ISSN:0009-4293
2673-2424