Hexakis(N,N-dimethyl-formamide-κO)cobalt(II) bis-(perchlorate)

Hexakis(N,N-dimethyl-formamide-κO)cobalt(II) bis-(perchlorate)

The asymmetric unit of the title complex, [Co(DMF)(6)](ClO(4))(2) (DMF = N,N-dimethyl-formamide, C(3)H(7)NO), consists of two half complex cations with the Co(2+) metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co(2+) ion is coordinated by six mol-...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-02, Vol.66 (Pt 3), p.m279-m279
Hauptverfasser: Eissmann, Frank, Böhle, Tony, Mertens, Florian O R L, Weber, Edwin
Format: Artikel
Sprache:eng
Schlagworte:
Metal-Organic Papers
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Zusammenfassung:The asymmetric unit of the title complex, [Co(DMF)(6)](ClO(4))(2) (DMF = N,N-dimethyl-formamide, C(3)H(7)NO), consists of two half complex cations with the Co(2+) metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co(2+) ion is coordinated by six mol-ecules of DMF in a slightly distorted octa-hedral geometry. The crystal structure is mainly stabilized by coordinative, ionic and C-H⋯O hydrogen-bonding inter-actions.
ISSN:1600-5368
1600-5368
DOI:10.1107/s160053681000454x