Bis(cyclohexylammonium) tetrachlorido(oxalato)stannate(IV)

The title salt, (C6H14N)2[Sn(C2O4)Cl4], was obtained as a by-product from the reaction between 2C6H14N+·C2O42−·1.5H2O and SnCl2·2H2O. The cyclohexylammonium cation has a chair conformation. The complex anion consists of an oxalate anion chelating the SnCl4 moiety, resulting in a distorted octahedral...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-08, Vol.69 (8), p.m473-m474
Hauptverfasser: Sarr, Modou, Diasse-Sarr, Aminata, Diallo, Waly, Plasseraud, Laurent, Cattey, Hélène
Format: Artikel
Sprache:eng
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Zusammenfassung:The title salt, (C6H14N)2[Sn(C2O4)Cl4], was obtained as a by-product from the reaction between 2C6H14N+·C2O42−·1.5H2O and SnCl2·2H2O. The cyclohexylammonium cation has a chair conformation. The complex anion consists of an oxalate anion chelating the SnCl4 moiety, resulting in a distorted octahedral coordination sphere of the SnIV atom with the O atoms in equatorial cis positions. In the crystal, cations and anions are linked through N-H...O and N-H...Cl interactions into a layered arrangement parallel to (100).
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813019284