Crystal structure of AlPCl8

Crystal structure of AlPCl8

The crystal structure of aluminium phosphorus chloride (systematic name: phosphorus tetrachloride tetrachloridoaluminate), (PCl4)[AlCl4] or AlPCl8, was determined and refined using single-crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Pbcm. The asymmetric u...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2024-12, Vol.80 (12), p.1280-1282
Hauptverfasser: Hyeonjin Seo, Seungyong Shin, Seung-Tae Hong
Format: Artikel
Sprache:eng
Schlagworte:
aluminium phosphorus chloride
aluminium(iii) chloride
crystal structure
phosphorus(v) chloride
single-crystal
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Zusammenfassung:The crystal structure of aluminium phosphorus chloride (systematic name: phosphorus tetrachloride tetrachloridoaluminate), (PCl4)[AlCl4] or AlPCl8, was determined and refined using single-crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Pbcm. The asymmetric unit comprises one Al atom, one P atom, and five Cl atoms. The structure is characterized by isolated AlCl4 and PCl4 tetrahedra, isostructural with FePCl8 and GaPCl8.
ISSN:2056-9890
DOI:10.1107/S2056989024010661