Synthesis of Planar Chiral Ferroceneformaldehydes via Rh(I)-Catalyzed C-H Arylation

Synthesis of Planar Chiral Ferroceneformaldehydes via Rh(I)-Catalyzed C-H Arylation

A general synthetic entry into 1,2-disubstituted chiral planar ferrocene derivatives has been developed based on an enantioselective Rh(I)-catalyzed C−H arylation.

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Veröffentlicht in:ACS central science 2023-11, Vol.9 (11), p.2002-2005
Hauptverfasser: Hendricks, Hailey, Roque, Jose B
Format: Artikel
Sprache:eng
Schlagworte:
Aldehydes
Cancer
Carbon
Catalysis
Chemistry
Enantiomers
Experiments
First Reactions
Ligands
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Zusammenfassung:A general synthetic entry into 1,2-disubstituted chiral planar ferrocene derivatives has been developed based on an enantioselective Rh(I)-catalyzed C−H arylation.
ISSN:2374-7943
2374-7951
DOI:10.1021/acscentsci.3c01225