Bis{2-[(E)-(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolato-κN,O}nickel(II)
In the title compound, [Ni(C(15)H(13)FNO(2))(2)], the Ni(II) atom is tetra-coordinated by two N atoms and two O atoms from two 2-[(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni(II) atom are trans to each other,...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-08, Vol.67 (Pt 8), p.m1010-m1011 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In the title compound, [Ni(C(15)H(13)FNO(2))(2)], the Ni(II) atom is tetra-coordinated by two N atoms and two O atoms from two 2-[(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni(II) atom are trans to each other, as the Ni(II) atom lies on an inversion centre. In the fluoro-phenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex mol-ecules are linked via inter-molecular C-H⋯F hydrogen bonds, forming chains along [001]. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536811025189 |