Bis[2,6-bis-(benzimidazol-2-yl)pyridine-κ 3 N , N ', N '']nickel(II) bis-(tri-fluoro-methane-sulfonate) diethyl ether monosolvate

In the title complex, [Ni(C H N ) ](CF SO ) ·(CH CH ) O, the central Ni atom is sixfold coordinated by three nitro-gen atoms of each 2,6-bis-(2-benzimidazol-yl)pyridine ligand in a distorted octa-hedral geometry with two tri-fluoro-methane-sulfonate ions and a mol-ecule of diethyl ether completing t...

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Veröffentlicht in:IUCrData 2024-01, Vol.9 (Pt 1), p.x240088-x240088, Article x240088
Hauptverfasser: Ruiz, Sarah E, Arman, Hadi D, Adrian, Rafael A
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title complex, [Ni(C H N ) ](CF SO ) ·(CH CH ) O, the central Ni atom is sixfold coordinated by three nitro-gen atoms of each 2,6-bis-(2-benzimidazol-yl)pyridine ligand in a distorted octa-hedral geometry with two tri-fluoro-methane-sulfonate ions and a mol-ecule of diethyl ether completing the outer coordination sphere of the complex. Hydrogen bonding contributes to the organization of the asymmetric units in columns along the axis generating a porous supra-molecular structure. The structure was refined as a two-component twin with a refined BASF value of 0.4104 (13).
ISSN:2414-3146
2414-3146
DOI:10.1107/S2414314624000889