Bis[2,6-bis-(benzimidazol-2-yl)pyridine-κ 3 N , N ', N '']nickel(II) bis-(tri-fluoro-methane-sulfonate) diethyl ether monosolvate
In the title complex, [Ni(C H N ) ](CF SO ) ·(CH CH ) O, the central Ni atom is sixfold coordinated by three nitro-gen atoms of each 2,6-bis-(2-benzimidazol-yl)pyridine ligand in a distorted octa-hedral geometry with two tri-fluoro-methane-sulfonate ions and a mol-ecule of diethyl ether completing t...
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Veröffentlicht in: | IUCrData 2024-01, Vol.9 (Pt 1), p.x240088-x240088, Article x240088 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | In the title complex, [Ni(C
H
N
)
](CF
SO
)
·(CH
CH
)
O, the central Ni
atom is sixfold coordinated by three nitro-gen atoms of each 2,6-bis-(2-benzimidazol-yl)pyridine ligand in a distorted octa-hedral geometry with two tri-fluoro-methane-sulfonate ions and a mol-ecule of diethyl ether completing the outer coordination sphere of the complex. Hydrogen bonding contributes to the organization of the asymmetric units in columns along the
axis generating a porous supra-molecular structure. The structure was refined as a two-component twin with a refined BASF value of 0.4104 (13). |
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ISSN: | 2414-3146 2414-3146 |
DOI: | 10.1107/S2414314624000889 |