Superhydrophobic‐Substrate‐Assisted Construction of Free‐Standing Microcavity‐Patterned Conducting Polymer Films

Patterned conducting polymer films with unique structures have promising prospects for application in various fields, such as actuation, water purification, sensing, and bioelectronics. However, their practical application is hindered because of the limitations of existing construction methods. Herein, a strategy is proposed for the superhydrophobic‐substrate‐assisted construction of free‐standing 3D microcavity‐patterned conducting polymer films (McPCPFs) at micrometer resolution. Easy‐peeling and nondestructive transfer properties are achieved through electrochemical polymerization along the solid/liquid/gas triphase interface on micropillar‐structured substrates. The effects of the wettability and geometrical parameters of the substrates on the construction of McPCPFs are systematically investigated in addition to the evolution of the epitaxial growth along the triphase interface at different polymerization times. The McPCPFs can be easily peeled from superhydrophobic surfaces using ethanol because of weak adhesion and nondestructively transferred to various substrates taking advantage of the capillarity. Furthermore, sensitive light‐driven McPCPF locomotion on organic liquid surfaces is demonstrated. Ultimately, a facile strategy for the construction of free‐standing 3D microstructure‐patterned conducting polymer films is proposed, which can improve productivity and applicability of the films in different fields and expand the application scope of superwettable interfaces. Superhydrophobic‐substrate‐assisted construction of free‐standing microcavity‐patterned conducting polymer films (McPCPFs) at micrometer resolution with easy‐peeling and nondestructive transfer properties is achieved through electrochemical polymerization along the triphase interface. The effects of the wettability and geometrical parameters of micropillar‐structured substrates on the construction of McPCPFs are systematically investigated, followed by an exploration of the epitaxial growth and a demonstration in light‐driven locomotion.